全文获取类型
收费全文 | 1274篇 |
免费 | 61篇 |
国内免费 | 275篇 |
专业分类
安全科学 | 79篇 |
废物处理 | 84篇 |
环保管理 | 131篇 |
综合类 | 627篇 |
基础理论 | 171篇 |
污染及防治 | 369篇 |
评价与监测 | 62篇 |
社会与环境 | 51篇 |
灾害及防治 | 36篇 |
出版年
2024年 | 1篇 |
2023年 | 19篇 |
2022年 | 53篇 |
2021年 | 44篇 |
2020年 | 28篇 |
2019年 | 24篇 |
2018年 | 32篇 |
2017年 | 48篇 |
2016年 | 50篇 |
2015年 | 59篇 |
2014年 | 85篇 |
2013年 | 111篇 |
2012年 | 91篇 |
2011年 | 92篇 |
2010年 | 88篇 |
2009年 | 82篇 |
2008年 | 80篇 |
2007年 | 68篇 |
2006年 | 89篇 |
2005年 | 46篇 |
2004年 | 38篇 |
2003年 | 48篇 |
2002年 | 41篇 |
2001年 | 44篇 |
2000年 | 40篇 |
1999年 | 31篇 |
1998年 | 23篇 |
1997年 | 37篇 |
1996年 | 12篇 |
1995年 | 16篇 |
1994年 | 13篇 |
1993年 | 9篇 |
1992年 | 13篇 |
1991年 | 13篇 |
1990年 | 4篇 |
1989年 | 4篇 |
1987年 | 6篇 |
1986年 | 2篇 |
1985年 | 6篇 |
1984年 | 5篇 |
1982年 | 2篇 |
1981年 | 5篇 |
1980年 | 4篇 |
1979年 | 2篇 |
1978年 | 1篇 |
1975年 | 1篇 |
排序方式: 共有1610条查询结果,搜索用时 15 毫秒
991.
A promising strategy for effectively incorporating metal-containing waste materials into a variety of ceramic products was devised in this study. Elemental analysis confirmed that copper was the predominant metal component in the collected electroplating sludge, and aluminum was the predominant constituent of waterworks sludge collected in Hong Kong. The use of waterworks sludge as an aluminum-rich precursor material to facilitate copper stabilization under thermal conditions provides a promising waste-to-resource strategy. When sintering the mixture of copper sludge and the 900 °C calcined waterworks sludge, the CuAl2O4 spinel phase was first detected at 650 °C and became the predominant product phase at temperatures higher than 850 °C. Quantification of the XRD pattern using the Rietveld refinement method revealed that the weight of the CuAl2O4 spinel phase reached over 50% at 850 °C. The strong signals of the CuAl2O4 phase continued until the temperature reached 1150 °C, and further sintering initiated the generation of the other copper-hosting phases (CuAlO2, Cu2O, and CuO). The copper stabilization effect was evaluated by the copper leachability of the CuAl2O4 and CuO via the prolonged leaching experiments at a pH value of 4.9. The leaching results showed that the CuAl2O4 phase was superior to the CuAlO2 and CuO phases for immobilizing hazardous copper over longer leaching periods. The findings clearly indicate that spinel formation is the most crucial metal stabilization mechanism when sintering multiphase copper sludge with aluminum-rich waterworks sludge, and suggest a promising and reliable technique for reusing both types of sludge waste for ceramic materials. 相似文献
992.
<正>高温季节,企业工会通常会为生产一线职工送去各种清凉饮料,但多数职工认为这仅是表面工作,应景行为,工会应从根本上关心职工的劳动保护工作。 相似文献
993.
994.
Semi-continuous anaerobic co-digestion of thickened waste activated sludge and fat, oil and grease 总被引:2,自引:0,他引:2
Co-digestion of thickened waste activated sludge (TWAS) and fat, oil and grease (FOG) was conducted semi-continuously under mesophilic conditions. The results showed that daily methane yield at the steady state was 598 L/kg VSadded when TWAS and FOG (64% of total VS) were co-digested, which was 137% higher than that obtained from digestion of TWAS alone. The biogas composition was stabilized at a CH4 and CO2 content of 66.8% and 29.5%, respectively. Micronutrients added to co-digestion did not improve the biogas production and digestion stabilization. With a higher addition of FOG (74% of total VS), the digester initially failed but was slowly self-recovered; however, the methane yield was only about 50% of a healthy reactor with the same organic loading rate. 相似文献
995.
Alex H.S. Chik Melissa B. Glier Mark Servos Chand S. Mangat Xiao-Li Pang Yuanyuan Qiu Patrick M. DAoust Jean-Baptiste Burnet Robert Delatoll Sarah Dorner Qiudi Geng John P. Giesy Robert Mike McKay Michael R. Mulvey Natalie Prystajecky Nivetha Srikanthan Yuwei Xie Bernadette Conant Steve E. Hrudey 《环境科学学报(英文版)》2021,33(9):218-229
996.
Guixiang Guo Xiuhua Zhu Fuyou Shi Anning Wang Wei Wang Jun Mu Quanli Wan Rong Zhang 《环境科学学报(英文版)》2013
Environmental friendly materials, K6SiW11O39Sn (SiWSn), was synthesized. SiWSn photocatalytic decomposition of C. I. Reactive Red 24 (RR24) with the UV-lamp (253.7 nm, 20 W), Xenon lamp filtered less than 390 nm light (500 W) and sun light was investigated. The results showed that RR24 solution could be effectively decolorized with the SiWSn photocatalyst. The photocatalytic degradation efficiency of RR24 with SiWSn was affected by the initial concentration of RR2 solution, the amount of SiWSn and the photolysis time. It is demonstrated that the process of photodegradation of RR24 with SiWSn is a pesudo first-order reaction, which can be described by Langmuir-Hinshelwood equation. Hydroxyl radicals and holes are both the main oxidants in the photocatalytic reaction of RR24 with SiWSn. 相似文献
997.
The decay of wood and other cellulosic materials by fungi cause significant economic loss. The widely used chromated copper arsenate was prohibited for the environmental impact and safety of arsenic and chromium. It was found that natural product hinokitiol (HK) had fungicidal and insecticidal activities, and its toxicity was bearable for the environment. We described the practical synthesis of HK-K salt. According to the GB/T18261-2000 and LY/T1283-1998, wood preservative performance of HK-K salt was tested. The results showed that the best inhibitory concentration of HK-K salt was 50 mg/L, for which the prevention effectiveness on mold is better, the killed value is between 0 and 1, and the corrosion-resistant for wood-rotting fungi is grade A. 相似文献
998.
针对目前煤气吹脱解吸法处理焦化剩余氨水的过程中,碱的耗量较高的现状,结合具有专利技术的复合解吸塔,通过现场中试试验,研究了增加保温装置,改变加碱的位置,并适当增加了废水的停留时间的影响。最佳操作条件为:中位加碱,吹脱次数n=3,煤气温度T g=70℃,废水温度T w=90℃,pH=11,表面活性剂加入量ρ=10 mg/L,气液比q=350∶1,处理后的废水氨氮含量为248.2 mg/L,氨氮去除率可达到92.75%。最终的碱耗量为5.9 kg/m3,比原来的碱耗量降低了46.36%。 相似文献
999.
为了研究含铬浸出渣的调质解毒机理,建立了CaO-MgO-FeO-Na2O-SiO2-Al2O3-Cr2O3七元渣系活度模型,基于共存理论的活度模型得出了铬渣中主要组分及复合氧化物在不同条件下的活度。所得的结果表明,铬渣中Cr2O3主要形成了Na2Cr2O4和CaCr2O4,这两种复合氧化物不稳定,在自然环境中分别会被氧化为水溶性的铬酸钠(Na2CrO4)和酸溶性的铬酸钙(CaCrO4),释放出具有强毒性的Cr(Ⅵ),是造成铬污染的主要原因。温度、碱度以及渣中FeO含量都能影响渣系组分的活度。在1700K下,将铬渣碱度调至1.14,并加入30%的FeO能够使Cr2O3的有效固定率提高至88.2%,基本实现了铬渣的解毒。 相似文献
1000.
A home-made inexpensive passive diffusion bag (PDB) sampler, prepared by filling deionized water in low-density polyethylene (LDPE) tubes, was evaluated for volatile organic compounds (VOC) sampling in groundwater at industrial contamination sites. Impacts of environmentally relevant conditions on the sampling equilibration time and partitioning of VOCs between the sampler and the water sample were investigated. Sample salinity, agitation and temperature can influence the equilibration time, but generally sampling equilibration was obtained in 14 days under real field sampling of VOCs in groundwater. Both laboratory study and field testing in a contaminated site showed that the VOC concentrations in the developed sampler were equal to those in the water samples at equitibrium. Coupled with a purge and trap concentrator-gas chromatograph-mass spectrometer (P&T-GC-MS), the developed PDB sampler provided a low-cost sampling device for routine monitoring of VOCs in groundwater in wells, with LODs in the range of 2.9-10 μg/L. The proposed PDB was applied to determine VOCs in groundwater at an industrial contamination site, and the present results agreed well with those determined using conventional pump-and-sample monitoring. All the studied 13 VOCs were tested in the four wells in the industrial contamination sites, with their concentrations in the range of 12-73660 μg/L. In addition, while benzene and toluene were heavily contaminated up to a maximum concentration of 74000 μg/L and 6000 μg/L, respectively, 1,2,3-trichlorobenzene and bromobenzene had relatively low contamination levels (below 25 μg/L). 相似文献